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Calcimator

Quantum Dot Calculator

Emission wavelength and bandgap from quantum dot size (Brus equation).

Inputs

Results

Emission Wavelength (nm)

626.7

Effective Bandgap (eV)

1.98

Confinement Energy (eV)0.32
Coulomb Correction (eV)0.08
Color (1=UV...7=Red, 8=IR)7
Photon Energy (eV)1.98
Coulomb Ev0.08
How to Use This Calculator
  1. Enter the quantum dot radius (nm) — smaller dots produce higher-energy (blue-shifted) emission.
  2. Set the bulk bandgap (eV) and effective mass ratio (m*/m_e) for your semiconductor material.
  3. Enter the dielectric constant for Coulomb correction accuracy.
  4. Review emission wavelength (nm), effective bandgap (eV), quantum confinement energy, and Coulomb correction.
  5. Use the color code output to correlate dot size with visible emission color for display or bio-imaging applications.

How the result changes with Bulk Bandgap (eV)

Bulk Bandgap (eV)Emission Wavelength (nm)Effective Bandgap (eV)
1.099331.33
3.56326.53.8
6.541836.78
9.01134.19.25

What each input means

QD Radius (nm)
Quantum dot radius. CdSe QDs: typically 1-5 nm.
Bulk Bandgap (eV)
Bulk semiconductor bandgap. CdSe=1.74, CdS=2.42, InP=1.35.
Effective Mass (m*/m_e)
Reduced effective mass ratio. CdSe~0.13, CdS~0.21.
Dielectric Constant
Relative permittivity. CdSe=10.6, CdS=5.7.

What each result means

Emission Wavelength (nm)
Peak emission wavelength from Brus equation.
Effective Bandgap (eV)
Size-dependent bandgap energy.
Confinement Energy (eV)
Quantum confinement contribution.
Coulomb Correction (eV)
Electron-hole attraction correction.
Color (1=UV...7=Red, 8=IR)
Approximate visible color classification.
Photon Energy (eV)
Energy of emitted photon.

How this is calculated

Worked example, using the default values

  1. Identify Input Parameters
    4 parameters
    QD Radius (nm) = 3, Bulk Bandgap (eV) = 1.74, Effective Mass (m*/m_e) = 0.13, Dielectric Constant = 10.6 = 4 input(s) provided
  2. Calculate Emission Wavelength
    Emission Wavelength = emissionWavelengthM * 1e9
    626.7 = 626.7
  3. Calculate Effective Bandgap
    Effective Bandgap = max(bulkBandgapEv, totalBandgapEv)
    1.98 = 1.98
  4. Calculate Confinement Energy
    Confinement Energy = (h * h) / (8 * mEff * R * R) / e
    0.321 = 0.321
  5. Calculate Coulomb Correction
    Coulomb Correction = coulombCorrection / e
    0.082 = 0.082

Engine last updated . Checked against 3 independently-derived tests how we verify calculators.

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