Quantum Dot Calculator
Emission wavelength and bandgap from quantum dot size (Brus equation).
Inputs
Results
Emission Wavelength (nm)
626.7
Effective Bandgap (eV)
1.98
Confinement Energy (eV)0.32
Coulomb Correction (eV)0.08
Color (1=UV...7=Red, 8=IR)7
Photon Energy (eV)1.98
Coulomb Ev0.08
How to Use This Calculator
- Enter the quantum dot radius (nm) — smaller dots produce higher-energy (blue-shifted) emission.
- Set the bulk bandgap (eV) and effective mass ratio (m*/m_e) for your semiconductor material.
- Enter the dielectric constant for Coulomb correction accuracy.
- Review emission wavelength (nm), effective bandgap (eV), quantum confinement energy, and Coulomb correction.
- Use the color code output to correlate dot size with visible emission color for display or bio-imaging applications.
How the result changes with Bulk Bandgap (eV)
| Bulk Bandgap (eV) | Emission Wavelength (nm) | Effective Bandgap (eV) |
|---|---|---|
| 1.09 | 933 | 1.33 |
| 3.56 | 326.5 | 3.8 |
| 6.54 | 183 | 6.78 |
| 9.01 | 134.1 | 9.25 |
What each input means
- QD Radius (nm)
- Quantum dot radius. CdSe QDs: typically 1-5 nm.
- Bulk Bandgap (eV)
- Bulk semiconductor bandgap. CdSe=1.74, CdS=2.42, InP=1.35.
- Effective Mass (m*/m_e)
- Reduced effective mass ratio. CdSe~0.13, CdS~0.21.
- Dielectric Constant
- Relative permittivity. CdSe=10.6, CdS=5.7.
What each result means
- Emission Wavelength (nm)
- Peak emission wavelength from Brus equation.
- Effective Bandgap (eV)
- Size-dependent bandgap energy.
- Confinement Energy (eV)
- Quantum confinement contribution.
- Coulomb Correction (eV)
- Electron-hole attraction correction.
- Color (1=UV...7=Red, 8=IR)
- Approximate visible color classification.
- Photon Energy (eV)
- Energy of emitted photon.
How this is calculated
Worked example, using the default values
- Identify Input Parameters4 parametersQD Radius (nm) = 3, Bulk Bandgap (eV) = 1.74, Effective Mass (m*/m_e) = 0.13, Dielectric Constant = 10.6 = 4 input(s) provided
- Calculate Emission WavelengthEmission Wavelength = emissionWavelengthM * 1e9626.7 = 626.7
- Calculate Effective BandgapEffective Bandgap = max(bulkBandgapEv, totalBandgapEv)1.98 = 1.98
- Calculate Confinement EnergyConfinement Energy = (h * h) / (8 * mEff * R * R) / e0.321 = 0.321
- Calculate Coulomb CorrectionCoulomb Correction = coulombCorrection / e0.082 = 0.082
Engine last updated . Checked against 3 independently-derived tests — how we verify calculators.
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